There's still considerable debate in the research literature on the relationship between cPTSD and BPD, and features that distinguish each. As you note, there is a lot of comorbidity. I myself qualify for a diagnosis of cPTSD, but would never qualify for a diagnosis of BPD. Some of the symptoms you list for your ex really leave me thinking BPD.
In case you might find it helpful, here's some material from recently published studies:
"While BPD and CPTSD do exhibit overlap in the type of difficulties across affect regulation, self-concept, and interpersonal relationships, there are also important distinctions that are reflected in how symptoms manifest for either CPTSD or BPD. For example, in CPTSD, there is a persistent negative sense of self, while in BPD there is an unstable sense of self that can be internalizing or positive and may change back and forth between the two. Interpersonal difficulties in CPTSD are often characterized by avoidance and disconnection, while in BPD, they may include relationships marked by either ongoing or intermittent volatility and by efforts to connect with others to avoid feelings of abandonment (Cloitre et al., 2014). BPD is also marked by more extreme strategies to regulate affect. For example, suicidal or self-harming behaviors often result from attempts to escape from or change emotions that seem intolerable (Conklin et al., 2006)."
"...These relationships with external correlates may be useful in identifying key features of each disorder that distinguish them from one another despite their substantial overlap, such as angry outbursts more often amounting to aggression or violent behavior in BPD compared to CPTSD (ICD-11 PTSD and DSO) or pervasive attempts to avoid internal and external trauma stimuli in CPTSD (ICD-11 PTSD and DSO) compared to BPD."
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9107503/
"Overall results indicate that the distinction between BPD and CPTSD symptoms was strongly supported. However, our results also suggest that two symptoms of CPTSD, namely, “When I am upset, it takes me a long time to calm down.” (AD1) and “I feel numb or emotionally shut down” (AD2), were the only symptoms connecting the BPD with CPTSD constructs and potentially contribute to the overlap of the two conditions (Powers et al., 2022; Frost et al., 2020)."
https://www.researchgate.net/publication/366964802_Borderline_Personality_Disorder_BPD_and_Complex_Post_Traumatic_Stress_Disorder_CPTSD_A_network_analysis_in_a_highly_traumatised_clinical_sample
"...the DSO [Disturbances of Self-Organization] symptoms of cPTSD are consistent with the flight response, which is characterized by both unmodulated distress (i.e., DSO’s difficulty in self-calming, guilt, and sense of worthlessness) and both conscious and unconscious attempts to escape from further harm (i.e., DSO’s emotional numbing and relational detachment). Flight responses involve active attempts to restore safety by disengaging from sources of harm (e.g., fear of closeness) and distress, which are highly self-referential (i.e., associated with the DMN [Default Mode Network]) and include attempts to mobilize executive problem solving and decision-making (i.e., associated with the PfC [prefrontal cortex]). Thus, cPTSD could be understood as the maladaptive persistence of initially adaptive stress reactions that progress from hypervigilance (i.e., PTSD) to emotional/relational shut-down (i.e., DSO).
BPD could emerge as a fight response when executive control capabilities are not sufficient to sustain PTSD’s freeze/hypervigilance and cPTSD’s flight/detachment, which is consistent with evidence of diminished connectivity within the salience network and the DMN, and hypoactivation of the PfC plus hyperactivation of the amygdala, in BPD. Instead of attempts to cope by means of vigilance or detachment, BPD involves reacting in a fight mode with impulsive, disorganized, and hostile behavior in relationships and limited or no sense of self-awareness and self-efficacy. The fight reaction characterizing BPD includes a surge in bodily arousal initiated by the brain’s innate alarm system [102], and desperate attempts to prevent or retaliate for perceived or real abandonment. The alternating enmeshment in and rejection of relationships characterizing BPD also is consistent with the emotional dysregulation and deficits in executive function that have been found to occur among individuals who are experiencing disorganized attachment."
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8103648/