So my parents were married for 29 years and in 2022, my dad decided he had had enough of my moms behavior and filed for divorce. Mom HATES him with a burning passion and has really tried to push myself (29M) and my brother (31) to cut him out of our lives entirely for the betrayal and how much he hurt her.
One red flag is your mom's hate. Another red flag is her thinking that because she hates him you should cut him out of your life. She is effectively saying you must choose him or her. That is emotionally immature, very unhealthy, and without any boundaries for letting you have your autonomy to make your own decisions in life. I'm so sorry.
My brother nor I have told our mom that it's happening yet and we know it's going to get bad. My SIL says she absolutely will be posting pictures on facebook and refuses to set it so mom can't view it - taking some moral stand I suppose without understanding the hell this will reign down on her husband and myself. My brother and I are both groomsmen and my nephew is the ring bearer which will set her off even further. How should we handle this situation? Tell her now, wait until the facebook posts spill the secrets? Hack her facebook and block and unfollow anyone that might post/tag someone from the wedding?

Let's look at this from another angle. Your mom and dad are divorced. Since your dad is remarrying, I'm "guessing" they don't have contact with each other any more. So, if they don't have contact and talk to each other, what he does in his life is no concern of hers. She has no "right" to his information, unless he chooses to give it to her. You have no actual obligation to tell her about the wedding and your role in it. The fact that she has made you feel otherwise and this is causing you anxiety speaks to the real problem.
You sound worried about your mom's reaction when she finds out about the wedding. I'm with NW. This "isn't your problem". This is her problem. Let her self-soothe in her own way when she eventually finds out. It's not your job to feed her "information about your dad" which she will then use to stir up a whole ton of drama in advance (before you even perform your groomsmen job). Go enjoy the wedding, and then once she becomes aware of it, give her plenty of time and space to soothe herself if possible. Stay off the triangle. If she learns about it from SIL post, then that is for your brother and SIL to deal with.